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01 / 08

HAZARD AND PRECAUTIONARY STATEMENTS

GHS 危害和防护代码

Hazard Statements

(There are 72 individual and 17 combined Hazard statements)

Physical Hazards

H200          
                Unstable explosives.                                                                                                                                                
H201                Explosive; mass explosion hazard.
H202                Explosive, severe projection hazard.
H203                Explosive; fire, blast or projection hazard.
H204                Fire or projection hazard.
H205                May mass explode in fire.
H220                Extremely flammable gas.
H221                Flammable gas.
H222                Extremely flammable aerosol.
H223                Flammable aerosol.
H224                Extremely flammable liquid and vapour.
H225                Highly flammable liquid and vapour.
H226                Flammable liquid and vapour.
H227                Combustible liquid.
H228                Flammable solid.
H240                Heating may cause an explosion.
H241                Heating may cause a fire or explosion.
H242                Heating may cause a fire.
H250                Catches fire spontaneously if exposed to air.
H251                Self-heating: may catch fire.
H252                Self-heating in large quantities; may catch fire.
H260                In contact with water releases flammable gases which may ignite spontaneously.
H261                In contact with water releases flammable gas.
H270                May cause or intensify fire; oxidizer.
H271                May cause fire or explosion; strong oxidizer.
H272                May intensify fire; oxidizer.
H280                Contains gas under pressure; may explode if heated.
H281                Contains refrigerated gas; may cause cryogenic burns or injury.
H290                May be corrosive to metals.

Precautionary Statements

(There are 116 individual and 33 combined Precautionary statements)

Precautionary statements - General

P101 If medical advice is needed,have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use


Precautionary statements - Prevention

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P211 Do not spray on an open flame or other ignition source.
P220 Keep/Store away from clothing/…/combustible materials.
P221 Take any precaution to avoid mixing with combustibles/…
P222 Do not allow contact with air.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230 Keep wetted with …
P231 Handle under inert gas.
P232 Protect from moisture.
P233 Keep container tightly closed.
P234 Keep only in original container.
P235 Keep cool.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P244 Keep reduction valves free from grease and oil.
P250 Do not subject to grinding/shock/…/friction.
P251 Pressurized container: Do not pierce or burn, even after use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P263 Avoid contact during pregnancy/while nursing.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P282 Wear cold insulating gloves/face shield/eye protection.
P283 Wear fire/flame resistant/retardant clothing.
P284 Wear respiratory protection.
P285 In case of inadequate ventilation wear respiratory protection.
P231+P232 Handle under inert gas. Protect from moisture.
P235+P410 Keep cool. Protect from sunlight.


Precautionary statements - Response

P301 IF SWALLOWED:
P304 IF INHALED:
P305 IF IN EYES:
P306 IF ON CLOTHING:
P307 IF exposed:
P308 IF exposed or concerned:
P309 IF exposed or if you feel unwell:
P310 Immediately call a POISON CENTER or doctor/physician.
P311 Call a POISON CENTER or doctor/physician.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P313 Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P315 Get immediate medical advice/attention.
P320 Specific treatment is urgent (see … on this label).
P321 Specific treatment (see … on this label).
P322 Specific measures (see …on this label).
P330 Rinse mouth.
P331 Do NOT induce vomiting.
P332 IF SKIN irritation occurs:
P333 If skin irritation or rash occurs:
P334 Immerse in cool water/wrap n wet bandages.
P335 Brush off loose particles from skin.
P336 Thaw frosted parts with lukewarm water. Do not rub affected area.
P337 If eye irritation persists:
P338 Remove contact lenses, if present and easy to do. Continue rinsing.
P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341 If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342 If experiencing respiratory symptoms:
P350 Gently wash with plenty of soap and water.
P351 Rinse cautiously with water for several minutes.
P352 Wash with plenty of soap and water.
P353 Rinse skin with water/shower.
P360 Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361 Remove/Take off immediately all contaminated clothing.
P362 Take off contaminated clothing and wash before reuse.
P363 Wash contaminated clothing before reuse.
P370 In case of fire:
P371 In case of major fire and large quantities:
P372 Explosion risk in case of fire.
P373 DO NOT fight fire when fire reaches explosives.
P374 Fight fire with normal precautions from a reasonable distance.
P376 Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378 Use … for extinction.
P380 Evacuate area.
P381 Eliminate all ignition sources if safe to do so.
P390 Absorb spillage to prevent material damage.
P391 Collect spillage. Hazardous to the aquatic environment
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P334 IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338
P306+P360 IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307+P311 IF exposed: call a POISON CENTER or doctor/physician.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P309+P311 IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P333+P313 IF SKIN irritation or rash occurs: Get medical advice/attention.
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337+P313 IF eye irritation persists: Get medical advice/attention.
P342+P311 IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370+P376 in case of fire: Stop leak if safe to Do so.
P370+P378 In case of fire: Use … for extinction.
P370+P380 in case of fire: Evacuate area.
P370+P380+P375 in case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371+P380+P375 in case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.


Precautionary statements — Storage

P401 Store …
P402 Store in a dry place.
P403 Store in a well-ventilated place.
P404 Store in a closed container.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405 Store locked up.
P406 Store in corrosive resistant/… container with a resistant inner liner.
P407 Maintain air gap between stacks/pallets.
P410 Protect from sunlight.
P411 Store at temperatures not exceeding … oC/…oF.
P412 Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413 Store bulk masses greater than … kg/…lbs at temperatures not exceeding … oC/…oF.
P420 Store away from other materials.
P422 Store contents under …
P402+P404 Store in a dry place. Store in a closed container.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411+P235 Store at temperatures not exceeding … oC/…oF. Keep cool.


Precautionary statements — Disposal

P501 Dispose of contents/container to..…
P502 Refer to manufacturer/supplier for information on recovery/recycling



01 / 08

Risk Phrases


Indication of Particular Risks

R1:                       Explosive when dry                                                                                                                                            
2:                      Risk of explosion by shock, friction, fire or other sources of ignition
3:                      Extreme risk of explosion by shock, friction, fire or other sources of ignition
4:                      Forms very sensitive explosive metallic compounds
5:                      Heating may cause an explosion
6:                      Explosive with or without contact with air
7:                      May cause fire
8:                      Contact with combustible material may cause fire
9:                      Explosive when mixed with combustible material
10:                      Flammable
11:                      Highly Flammable
12:                      Extremely Flammable
14:                      Reacts violently with water
15:                      Contact with water liberates extremely flammable gases
16:                      Explosive when mixed with oxidizing substances
17:                      Spontaneously flammable in air
18:                      In use may form flammable/explosive vapor-air mixture
19:                      May form explosive peroxides
20:                      Harmful by inhalation
21:                      Harmful in contact with skin
22:                      Harmful if swallowed
23:                      Toxic by inhalation
24:                      Toxic in contact with skin
25:                      Toxic if swallowed
26:                      Very Toxic by inhalation
27:                      Very Toxic in contact with skin
28:                      Very Toxic if swallowed
29:                      Contact with water liberates toxic gas
30:                      Can become highly flammable in use
31:                      Contact with acids liberates toxic gas
32:                      Contact with acids liberates very toxic gas
33:                      Danger of cumulative effects
34:                      Causes burns
35:                      Causes severe burns
36:                      Irritating to the eyes
37:                      Irritating to the respiratory system
38:                      Irritating to the skin
39:                      Danger of very serious irreversible effects
40:                      Limited evidence of a carcinogenic effect
41:                      Risk of serious damage to eyes
42:                      May cause sensitization by inhalation
43:                      May cause sensitization by skin contact
44:                      Risk of explosion if heated under confinement
45:                      May cause cancer
46:                      May cause heritable genetic damage
48:                      Danger of serious damage to health by prolonged exposure
49:                      May cause cancer by inhalation
50:                      Very Toxic to aquatic organisms
51:                      Toxic to aquatic organisms
52:                      Harmful to aquatic organisms
53:                      May cause long-term adverse effects in the aquatic environment
54:                      Toxic to flora
55:                      Toxic to fauna
56:                      Toxic to soil organisms
57:                      Toxic to bees
58:                      May cause long-term adverse effects in the environment
59:                      Dangerous for the ozone layer
60:                      May impair fertility
61:                      May cause harm to the unborn child
62:                      Possible risk of impaired fertility
63:                      Possible risk of harm to the unborn child
64:                      May cause harm to breast-fed babies
65:                      Harmful: May cause lung damage if swallowed
66:                      Repeated exposure may cause skin dryness or cracking
67:                      Vapors may cause drowsiness and dizziness
68:                      Possible risk of irreversible effects


Combination of Particular Risks

R14/15:                      Reacts violently with water, liberating extremely flammable gases
15/29:                      Contact with water liberates toxic, extremely flammable gas
20/21:                      Harmful by inhalation and in contact with skin
20/21/22:                      Harmful by inhalation, in contact with skin and if swallowed
20/22:                      Harmful by inhalation and if swallowed
21/22:                      Harmful in contact with skin and if swallowed
23/24:                      Toxic by inhalation and in contact with skin
23/24/25:                      Toxic by inhalation, in contact with skin and if swallowed
23/25:                      Toxic by inhalation and if swallowed
24/25:                      Toxic in contact with skin and if swallowed
26/27:                      Very Toxic by inhalation and in contact with skin
26/27/28:                      Very Toxic by inhalation, in contact with skin and if swallowed
26/28:                      Very Toxic by inhalation and if swallowed
27/28:                      Very Toxic in contact with skin and if swallowed
36/37:                      Irritating to eyes and respiratory system
36/37/38:                      Irritating to eyes, respiratory system and skin
36/38:                      Irritating to eyes and skin
37/38:                      Irritating to respiratory system and skin
39/23:                      Toxic: danger of very serious irreversible effects through inhalation
39/23/24:                      Toxic: danger of very serious irreversible effects through inhalation in contact with skin
39/23/24/25:                      Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
39/23/25:                      Toxic: danger of very serious irreversible effects through inhalation and if swallowed
39/24:                      Toxic: danger of very serious irreversible effects in contact with skin
39/24/25:                      Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
39/25:                      Toxic: danger of very serious irreversible effects if swallowed
39/26:                      Very Toxic: danger of very serious irreversible effects through inhalation
39/26/27:                      Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
39/26/27/28:                      Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
39/26/28:                      Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed
39/27:                      Very Toxic: danger of very serious irreversible effects in contact with skin
39/27/28:                      Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
39/28:                      Very Toxic: danger of very serious irreversible effects if swallowed
42/43:                      May cause sensitization by inhalation and skin contact
48/20:                      Harmful: danger of serious damage to health by prolonged exposure through inhalation
48/20/21:                      Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
48/20/21/22:                      Harmful: danger of serious damage to health by prolonged exposure through inhalation, and in contact with skin and if swallowed
48/20/22:                      Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
48/21:                      Harmful: danger of serious damage to health by prolonged exposure in contact with skin
48/21/22:                      Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
48/22:                      Harmful: danger of serious damage to health by prolonged exposure if swallowed
48/23:                      Toxic: danger of serious damage to health by prolonged exposure through inhalation
48/23/24:                      Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
48/23/24/25:                      Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
48/23/25:                      Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
48/24:                      Toxic: danger of serious damage to health by prolonged exposure in contact with skin
48/24/25:                      Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
48/25:                      Toxic: danger of serious damage to health by prolonged exposure if swallowed
50/53:                      Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
51/53:                      Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
52/53:                      Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
68/20:                      Harmful: possible risk of irreversible effects through inhalation
68/20/21:                      Harmful: possible risk of irreversible effects through inhalation and in contact with skin
68/20/21/22:                      Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
68/20/22:                      Harmful: possible risk of irreversible effects through inhalation and if swallowed
68/22:                      Harmful: possible risk of irreversible effects if swallowed
68/21:                      Harmful: possible risk of irreversible effects in contact with skin
68/21/22:                      Harmful: possible risk of irreversible effects in contact with skin and if swallowed
68/22:                      Harmful: possible risk of irreversible effects if swallowed

Safety Phrases

Indication of Safety Precautions

S1:                    Keep locked up
2:                    Keep out of the reach of children
3:                    Keep in a cool place
4:                    Keep away from living quarters
5:                    Keep contents under ... (appropriate liquid to be specified by the manufacturer)
6:                    Keep under ... (inert gas to be specified by the manufacturer)
7:                    Keep container tightly closed
8:                    Keep container dry
9:                    Keep container in a well-ventilated place
12:                    Do not keep the container sealed
13:                    Keep away from food, drink and animal feeding stuffs
14:                    Keep away from ... (incompatible materials to be indicated by the manufacturer)
15:                    Keep away from heat
16:                    Keep away from sources of ignition - No smoking
17:                    Keep away from combustible material
18:                    Handle and open container with care
20:                    When using, do not eat or drink
21:                    When using, do not smoke
22:                    Do not breathe dust
23:                    Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24:                    Avoid contact with skin
25:                    Avoid contact with eyes
26:                    In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
27:                    Take off immediately all contaminated clothing
28:                    After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
29:                    Do not empty into drains
30:                    Never add water to this product
33:                    Take precautionary measures against static discharges
35:                    This material and its container must be disposed of in a safe way
36:                    Wear suitable protective clothing
37:                    Wear suitable gloves
38:                    In case of insufficient ventilation, wear suitable respiratory equipment
39:                    Wear eye/face protection
40:                    To clean the floor and all objects contaminated by this material use ... to be specified by the manufacturer
41:                    In case of fire and/or explosion do not breathe fumes
42:                    During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified)
43:                    In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
45:                    In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
46:                    If swallowed, seek medical advice immediately and show this container or label
47:                    Keep at temperature not exceeding ... E C (to be specified by the manufacturer)
48:                    Keep wetted with ... (appropriate material to be specified by the manufacturer)
49:                    Keep only in the original container
50:                    Do not mix with ... (to be specified by the manufacturer)
51:                    Use only in well-ventilated areas
52:                    Not recommended for interior use on large surface areas
53:                    Avoid exposure - obtain special instruction before use
56:                    Dispose of this material and its container to hazardous or special waste collection point
57:                    Use appropriate container to avoid environmental contamination
59:                    Refer to manufacturer/supplier for information on recovery/recycling
60:                    This material and/or its container must be disposed of as hazardous waste
61:                    Avoid release to the environment. Refer to special instructions safety data sheet
62:                    If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
63:                    In case of accident by inhalation, remove casualty to fresh air and keep at rest
64:                    If swallowed, rinse mouth with water (only if the person is conscious)

Combination of Safety Precautions

1/2:                  Keep locked up and out of the reach of children
3/7:                  Keep container tightly closed in a cool place
3/9/14:                  Keep in a cool well-ventilated place away from ... incompatible materials to be indicated by manufacturer
3/9/14/49:                  Keep only in the original container in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)
3/9/49:                  Keep only in the original container in a cool well-ventilated place
3/14:                  Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer)
7/8:                  Keep container tightly closed and dry
7/9:                  Keep container tightly closed and in a well-ventilated place
7/47:                  Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by manufacturer)
20/21:                  When using, do not eat, drink or smoke
24/25:                  Avoid contact with skin and eyes
27/28:                  After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of.... (to be specified by the manufacturer)
29/35:                  Do not empty into drains, dispose of this container and it's material in a safe way
29/56:                  Do not empty into drains, dispose of this material and its container to hazardous or special waste-collection point
36/37:                  Wear suitable protective clothing and gloves
36/37/39:                  Wear suitable protective clothing, gloves and eye/face protection
36/39:                  Wear suitable protective clothing and eye/face protection
37/39:                  Wear suitable gloves and eye/face protection
47/49:                  Keep only in the original container at temperature not exceeding ... °C (to be specified by manufacturer

PICTOGRAMS AND HAZARD CODES

RS 危险和安全代码


01 / 08
案例名称: 特约经销商

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01 / 08
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